10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10 H -phenothiazine
The title compound, C 19 H 17 Cl 2 NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is...
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| creator | Umezono, Satoru Okuno, Tsunehisa |
| description | The title compound, C
19
H
17
Cl
2
NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 (7)°. The phenothiazine unit has a butterfly structure and the central six-membered ring adopts a boat conformation. The fold angle between the benzene rings is 28.52 (7)°. The crystal structure features weak C
sp
3
—H...Cl hydrogen bonds, H...S contacts and π–π stacking interactions between phenothiazine units. |
| doi_str_mv | 10.1107/S2414314618002328 |
| format | Article |
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19
H
17
Cl
2
NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 (7)°. The phenothiazine unit has a butterfly structure and the central six-membered ring adopts a boat conformation. The fold angle between the benzene rings is 28.52 (7)°. The crystal structure features weak C
sp
3
—H...Cl hydrogen bonds, H...S contacts and π–π stacking interactions between phenothiazine units.</description><identifier>ISSN: 2414-3146</identifier><identifier>EISSN: 2414-3146</identifier><identifier>DOI: 10.1107/S2414314618002328</identifier><language>eng</language><ispartof>IUCrData, 2018-02, Vol.3 (2), Article x180232</ispartof><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c908-a3855d741481c0e061e81629c4d0db397e477156de53c304140ee833df15cd493</citedby><cites>FETCH-LOGICAL-c908-a3855d741481c0e061e81629c4d0db397e477156de53c304140ee833df15cd493</cites><orcidid>0000-0001-5778-0333</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,864,27922,27923</link.rule.ids></links><search><creatorcontrib>Umezono, Satoru</creatorcontrib><creatorcontrib>Okuno, Tsunehisa</creatorcontrib><title>10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10 H -phenothiazine</title><title>IUCrData</title><description>The title compound, C
19
H
17
Cl
2
NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 (7)°. The phenothiazine unit has a butterfly structure and the central six-membered ring adopts a boat conformation. The fold angle between the benzene rings is 28.52 (7)°. The crystal structure features weak C
sp
3
—H...Cl hydrogen bonds, H...S contacts and π–π stacking interactions between phenothiazine units.</description><issn>2414-3146</issn><issn>2414-3146</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNplkEFLw0AUhBdRsNT-AG89Kvj0vewmu3uUaq1S8GBvIiHdfSGRNSnZeIi_3gQ9CJ5mGIbhY4Q4J7wmQn3zkihSklRGBjGRiTkSsymCKTv-40_FIsZ3RCSjjbVyJp4I4ZWuCO5qV4W2a0HBRd_VH9xXQ4h1GMLl_rMHAm5AwtBAAkN4A8LlZgmHipu2r-riq274TJyURYi8-NW52K3vd6sNbJ8fHle3W3AWDRTSpKnXI5Ehh4wZsaEssU559HtpNSutKc08p9JJHHvIbKT0JaXOKyvngn5mXdfG2HGZH0bcohtywny6I_93h_wGbLxN4g</recordid><startdate>20180228</startdate><enddate>20180228</enddate><creator>Umezono, Satoru</creator><creator>Okuno, Tsunehisa</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-5778-0333</orcidid></search><sort><creationdate>20180228</creationdate><title>10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10 H -phenothiazine</title><author>Umezono, Satoru ; Okuno, Tsunehisa</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c908-a3855d741481c0e061e81629c4d0db397e477156de53c304140ee833df15cd493</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Umezono, Satoru</creatorcontrib><creatorcontrib>Okuno, Tsunehisa</creatorcontrib><collection>CrossRef</collection><jtitle>IUCrData</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Umezono, Satoru</au><au>Okuno, Tsunehisa</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10 H -phenothiazine</atitle><jtitle>IUCrData</jtitle><date>2018-02-28</date><risdate>2018</risdate><volume>3</volume><issue>2</issue><artnum>x180232</artnum><issn>2414-3146</issn><eissn>2414-3146</eissn><abstract>The title compound, C
19
H
17
Cl
2
NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 (7)°. The phenothiazine unit has a butterfly structure and the central six-membered ring adopts a boat conformation. The fold angle between the benzene rings is 28.52 (7)°. The crystal structure features weak C
sp
3
—H...Cl hydrogen bonds, H...S contacts and π–π stacking interactions between phenothiazine units.</abstract><doi>10.1107/S2414314618002328</doi><orcidid>https://orcid.org/0000-0001-5778-0333</orcidid></addata></record> |
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| language | eng |
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| source | DOAJ Directory of Open Access Journals; EZB-FREE-00999 freely available EZB journals |
| title | 10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10 H -phenothiazine |
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