10-[1,1-Dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10 H -phenothiazine

The title compound, C 19 H 17 Cl 2 NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is...

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Veröffentlicht in:IUCrData 2018-02, Vol.3 (2), Article x180232
Hauptverfasser: Umezono, Satoru, Okuno, Tsunehisa
Format: Artikel
Sprache:eng
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Zusammenfassung:The title compound, C 19 H 17 Cl 2 NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 (7)°. The phenothiazine unit has a butterfly structure and the central six-membered ring adopts a boat conformation. The fold angle between the benzene rings is 28.52 (7)°. The crystal structure features weak C sp 3 —H...Cl hydrogen bonds, H...S contacts and π–π stacking interactions between phenothiazine units.
ISSN:2414-3146
2414-3146
DOI:10.1107/S2414314618002328