Synthesis and crystal structure of a solvated Co III complex with 2-hydroxy-3-methoxybenzaldehyde thiosemicarbazone ligands
The title Co III complex, bis[bis(2-hydroxy-3-methoxybenzaldehyde thiosemicarbazonato)cobalt(III)] dithionate–dimethylformamide–methanol (1/4/3), [Co(C 9 H 10 N 3 O 2 S) 2 ] 2 (S 2 O 6 )·4C 3 H 7 NO·3CH 3 OH, with monodeprotonated 2-hydroxy-3-methoxybenzaldehyde thiosemicarbazone as ligands crystall...
Gespeichert in:
| Veröffentlicht in: | Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2021-11, Vol.77 (11), p.1130-1134 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1134 |
|---|---|
| container_issue | 11 |
| container_start_page | 1130 |
| container_title | Acta crystallographica. Section E, Crystallographic communications |
| container_volume | 77 |
| creator | Rusanova, Julia A. Kokozay, Volodymyr N. Petrusenko, Svitlana Plyuta, Nataliya |
| description | The title Co
III
complex, bis[bis(2-hydroxy-3-methoxybenzaldehyde thiosemicarbazonato)cobalt(III)] dithionate–dimethylformamide–methanol (1/4/3), [Co(C
9
H
10
N
3
O
2
S)
2
]
2
(S
2
O
6
)·4C
3
H
7
NO·3CH
3
OH, with monodeprotonated 2-hydroxy-3-methoxybenzaldehyde thiosemicarbazone as ligands crystallizes in the space group
P
\overline{1}. The asymmetric unit consists of two mononuclear [Co
L
2
]
+
cations, one dithionate anion (S
2
O
6
)
2−
as counter-anion and seven solvate molecules (four dimethylmethanamide and three methanol). Each Co
III
ion has a moderately distorted octahedral S
2
N
2
O
2
geometry. In the crystal, the components are linked by numerous N—H...O and O—H...O contacts. |
| doi_str_mv | 10.1107/S2056989021010616 |
| format | Article |
| fullrecord | <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1107_S2056989021010616</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1107_S2056989021010616</sourcerecordid><originalsourceid>FETCH-LOGICAL-c175t-e41883500ba0551ac6b041f19d91e28faec2745f3ed69ea22bbda766aedc91f23</originalsourceid><addsrcrecordid>eNplkE9Lw0AUxBdRsNR-AG_7BaL7NtlNcpTin0LBQ_UcXnZfTCTJlt2tNvXL26IHwdMMv4EZGMauQdwAiPx2I4XSZVEKCQKEBn3GZieUnNj5H3_JFiG8CyEgU6lWcsa-NtMYWwpd4DhabvwUIvY8RL8zceeJu4YjD67_wEiWLx1frVbcuGHb055_drHlMmkn691-StJkoNgeXU3jAXtLx4B4bDsXaOgM-hoPbiTed2_HsXDFLhrsAy1-dc5eH-5flk_J-vlxtbxbJwZyFRPKoChSJUSNQilAo2uRQQOlLYFk0SAZmWeqScnqklDKuraYa41kTQmNTOcMfnqNdyF4aqqt7wb0UwWiOh1Y_Tsw_Qb3HWYE</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis and crystal structure of a solvated Co III complex with 2-hydroxy-3-methoxybenzaldehyde thiosemicarbazone ligands</title><source>DOAJ Directory of Open Access Journals</source><source>PubMed Central Open Access</source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><creator>Rusanova, Julia A. ; Kokozay, Volodymyr N. ; Petrusenko, Svitlana ; Plyuta, Nataliya</creator><creatorcontrib>Rusanova, Julia A. ; Kokozay, Volodymyr N. ; Petrusenko, Svitlana ; Plyuta, Nataliya</creatorcontrib><description>The title Co
III
complex, bis[bis(2-hydroxy-3-methoxybenzaldehyde thiosemicarbazonato)cobalt(III)] dithionate–dimethylformamide–methanol (1/4/3), [Co(C
9
H
10
N
3
O
2
S)
2
]
2
(S
2
O
6
)·4C
3
H
7
NO·3CH
3
OH, with monodeprotonated 2-hydroxy-3-methoxybenzaldehyde thiosemicarbazone as ligands crystallizes in the space group
P
\overline{1}. The asymmetric unit consists of two mononuclear [Co
L
2
]
+
cations, one dithionate anion (S
2
O
6
)
2−
as counter-anion and seven solvate molecules (four dimethylmethanamide and three methanol). Each Co
III
ion has a moderately distorted octahedral S
2
N
2
O
2
geometry. In the crystal, the components are linked by numerous N—H...O and O—H...O contacts.</description><identifier>ISSN: 2056-9890</identifier><identifier>EISSN: 2056-9890</identifier><identifier>DOI: 10.1107/S2056989021010616</identifier><language>eng</language><ispartof>Acta crystallographica. Section E, Crystallographic communications, 2021-11, Vol.77 (11), p.1130-1134</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c175t-e41883500ba0551ac6b041f19d91e28faec2745f3ed69ea22bbda766aedc91f23</citedby><cites>FETCH-LOGICAL-c175t-e41883500ba0551ac6b041f19d91e28faec2745f3ed69ea22bbda766aedc91f23</cites><orcidid>0000-0002-1835-5956 ; 0000-0003-1834-3020 ; 0000-0002-0801-1690 ; 0000-0001-8594-2643</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,864,27924,27925</link.rule.ids></links><search><creatorcontrib>Rusanova, Julia A.</creatorcontrib><creatorcontrib>Kokozay, Volodymyr N.</creatorcontrib><creatorcontrib>Petrusenko, Svitlana</creatorcontrib><creatorcontrib>Plyuta, Nataliya</creatorcontrib><title>Synthesis and crystal structure of a solvated Co III complex with 2-hydroxy-3-methoxybenzaldehyde thiosemicarbazone ligands</title><title>Acta crystallographica. Section E, Crystallographic communications</title><description>The title Co
III
complex, bis[bis(2-hydroxy-3-methoxybenzaldehyde thiosemicarbazonato)cobalt(III)] dithionate–dimethylformamide–methanol (1/4/3), [Co(C
9
H
10
N
3
O
2
S)
2
]
2
(S
2
O
6
)·4C
3
H
7
NO·3CH
3
OH, with monodeprotonated 2-hydroxy-3-methoxybenzaldehyde thiosemicarbazone as ligands crystallizes in the space group
P
\overline{1}. The asymmetric unit consists of two mononuclear [Co
L
2
]
+
cations, one dithionate anion (S
2
O
6
)
2−
as counter-anion and seven solvate molecules (four dimethylmethanamide and three methanol). Each Co
III
ion has a moderately distorted octahedral S
2
N
2
O
2
geometry. In the crystal, the components are linked by numerous N—H...O and O—H...O contacts.</description><issn>2056-9890</issn><issn>2056-9890</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNplkE9Lw0AUxBdRsNR-AG_7BaL7NtlNcpTin0LBQ_UcXnZfTCTJlt2tNvXL26IHwdMMv4EZGMauQdwAiPx2I4XSZVEKCQKEBn3GZieUnNj5H3_JFiG8CyEgU6lWcsa-NtMYWwpd4DhabvwUIvY8RL8zceeJu4YjD67_wEiWLx1frVbcuGHb055_drHlMmkn691-StJkoNgeXU3jAXtLx4B4bDsXaOgM-hoPbiTed2_HsXDFLhrsAy1-dc5eH-5flk_J-vlxtbxbJwZyFRPKoChSJUSNQilAo2uRQQOlLYFk0SAZmWeqScnqklDKuraYa41kTQmNTOcMfnqNdyF4aqqt7wb0UwWiOh1Y_Tsw_Qb3HWYE</recordid><startdate>20211101</startdate><enddate>20211101</enddate><creator>Rusanova, Julia A.</creator><creator>Kokozay, Volodymyr N.</creator><creator>Petrusenko, Svitlana</creator><creator>Plyuta, Nataliya</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-1835-5956</orcidid><orcidid>https://orcid.org/0000-0003-1834-3020</orcidid><orcidid>https://orcid.org/0000-0002-0801-1690</orcidid><orcidid>https://orcid.org/0000-0001-8594-2643</orcidid></search><sort><creationdate>20211101</creationdate><title>Synthesis and crystal structure of a solvated Co III complex with 2-hydroxy-3-methoxybenzaldehyde thiosemicarbazone ligands</title><author>Rusanova, Julia A. ; Kokozay, Volodymyr N. ; Petrusenko, Svitlana ; Plyuta, Nataliya</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c175t-e41883500ba0551ac6b041f19d91e28faec2745f3ed69ea22bbda766aedc91f23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rusanova, Julia A.</creatorcontrib><creatorcontrib>Kokozay, Volodymyr N.</creatorcontrib><creatorcontrib>Petrusenko, Svitlana</creatorcontrib><creatorcontrib>Plyuta, Nataliya</creatorcontrib><collection>CrossRef</collection><jtitle>Acta crystallographica. Section E, Crystallographic communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rusanova, Julia A.</au><au>Kokozay, Volodymyr N.</au><au>Petrusenko, Svitlana</au><au>Plyuta, Nataliya</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and crystal structure of a solvated Co III complex with 2-hydroxy-3-methoxybenzaldehyde thiosemicarbazone ligands</atitle><jtitle>Acta crystallographica. Section E, Crystallographic communications</jtitle><date>2021-11-01</date><risdate>2021</risdate><volume>77</volume><issue>11</issue><spage>1130</spage><epage>1134</epage><pages>1130-1134</pages><issn>2056-9890</issn><eissn>2056-9890</eissn><abstract>The title Co
III
complex, bis[bis(2-hydroxy-3-methoxybenzaldehyde thiosemicarbazonato)cobalt(III)] dithionate–dimethylformamide–methanol (1/4/3), [Co(C
9
H
10
N
3
O
2
S)
2
]
2
(S
2
O
6
)·4C
3
H
7
NO·3CH
3
OH, with monodeprotonated 2-hydroxy-3-methoxybenzaldehyde thiosemicarbazone as ligands crystallizes in the space group
P
\overline{1}. The asymmetric unit consists of two mononuclear [Co
L
2
]
+
cations, one dithionate anion (S
2
O
6
)
2−
as counter-anion and seven solvate molecules (four dimethylmethanamide and three methanol). Each Co
III
ion has a moderately distorted octahedral S
2
N
2
O
2
geometry. In the crystal, the components are linked by numerous N—H...O and O—H...O contacts.</abstract><doi>10.1107/S2056989021010616</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-1835-5956</orcidid><orcidid>https://orcid.org/0000-0003-1834-3020</orcidid><orcidid>https://orcid.org/0000-0002-0801-1690</orcidid><orcidid>https://orcid.org/0000-0001-8594-2643</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2056-9890 |
| ispartof | Acta crystallographica. Section E, Crystallographic communications, 2021-11, Vol.77 (11), p.1130-1134 |
| issn | 2056-9890 2056-9890 |
| language | eng |
| recordid | cdi_crossref_primary_10_1107_S2056989021010616 |
| source | DOAJ Directory of Open Access Journals; PubMed Central Open Access; PubMed Central; Free Full-Text Journals in Chemistry |
| title | Synthesis and crystal structure of a solvated Co III complex with 2-hydroxy-3-methoxybenzaldehyde thiosemicarbazone ligands |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T16%3A55%3A56IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20crystal%20structure%20of%20a%20solvated%20Co%20III%20complex%20with%202-hydroxy-3-methoxybenzaldehyde%20thiosemicarbazone%20ligands&rft.jtitle=Acta%20crystallographica.%20Section%20E,%20Crystallographic%20communications&rft.au=Rusanova,%20Julia%20A.&rft.date=2021-11-01&rft.volume=77&rft.issue=11&rft.spage=1130&rft.epage=1134&rft.pages=1130-1134&rft.issn=2056-9890&rft.eissn=2056-9890&rft_id=info:doi/10.1107/S2056989021010616&rft_dat=%3Ccrossref%3E10_1107_S2056989021010616%3C/crossref%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |