Crystal structure of ( Z )-4-[1-(4-acetylanilino)ethylidene]-3-methyl-1-phenyl-1 H -pyrazol-5(4 H )-one
In the solid state, the title compound, C 20 H 19 N 3 O 2 , adopts the keto–amine tautomeric form, with the H atom attached to the N atom, which participates in an intramolecular N—H...O hydrogen bond with an S (6) ring motif. The dihedral angles between the pyrazole ring and the phenyl and benzene...
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Veröffentlicht in: | Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2015-01, Vol.71 (1), p.94-96 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | In the solid state, the title compound, C
20
H
19
N
3
O
2
, adopts the keto–amine tautomeric form, with the H atom attached to the N atom, which participates in an intramolecular N—H...O hydrogen bond with an
S
(6) ring motif. The dihedral angles between the pyrazole ring and the phenyl and benzene rings are 3.69 (10) and 46.47 (9)°, respectively. In the crystal, molecules are linked by weak C—H...O hydrogen bonds, generating
C
(16) chains propagating in [301]. Weak aromatic π–π stacking interactions [centroid–centroid distances = 3.6123 (10) and 3.6665 (10) Å] link the chains into a three-dimensional network. |
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ISSN: | 2056-9890 2056-9890 |
DOI: | 10.1107/S2056989014026899 |