Crystal structure of ( Z )-4-[1-(4-acetylanilino)ethylidene]-3-methyl-1-phenyl-1 H -pyrazol-5(4 H )-one

In the solid state, the title compound, C 20 H 19 N 3 O 2 , adopts the keto–amine tautomeric form, with the H atom attached to the N atom, which participates in an intramolecular N—H...O hydrogen bond with an S (6) ring motif. The dihedral angles between the pyrazole ring and the phenyl and benzene...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2015-01, Vol.71 (1), p.94-96
Hauptverfasser: Mahfouz, Refaat M., Demircioğlu, Zeynep, Abbady, Mohamed S., Büyükgüngör, Orhan
Format: Artikel
Sprache:eng
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Zusammenfassung:In the solid state, the title compound, C 20 H 19 N 3 O 2 , adopts the keto–amine tautomeric form, with the H atom attached to the N atom, which participates in an intramolecular N—H...O hydrogen bond with an S (6) ring motif. The dihedral angles between the pyrazole ring and the phenyl and benzene rings are 3.69 (10) and 46.47 (9)°, respectively. In the crystal, molecules are linked by weak C—H...O hydrogen bonds, generating C (16) chains propagating in [301]. Weak aromatic π–π stacking interactions [centroid–centroid distances = 3.6123 (10) and 3.6665 (10) Å] link the chains into a three-dimensional network.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989014026899