Spiral tetrahedral packing in the β-Mn crystal as symmetry realization of the 8D E 8 lattice

Experimental values of atomic positions in the β-Mn crystal permit one to distinguish among them a fragment of the helix containing 15 interpenetrating distorted icosahedra, 90 vertices and 225 tetrahedra. This fragment corresponds to the closed helix of 15 icosahedra in the 4D {3, 3, 5} polytope. T...

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Veröffentlicht in:Acta crystallographica. Section A, Foundations and advances Foundations and advances, 2021-01, Vol.77 (Pt 1), p.7-18
Hauptverfasser: Talis, Alexander, Everstov, Ayal, Kraposhin, Valentin
Format: Artikel
Sprache:eng
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Zusammenfassung:Experimental values of atomic positions in the β-Mn crystal permit one to distinguish among them a fragment of the helix containing 15 interpenetrating distorted icosahedra, 90 vertices and 225 tetrahedra. This fragment corresponds to the closed helix of 15 icosahedra in the 4D {3, 3, 5} polytope. The primitive cubic lattice of these icosahedral helices envelopes not only all atoms of β-Mn, but also all tetrahedra belonging to the tiling of the β-Mn structure. The 2D projection of all atomic positions in the β-Mn unit cells shows that they are situated (by neglecting small differences) on three circumferences containing 2D projections of 90 vertices of the {3, 3, 5} polytope on the same plane. Non-crystallographic symmetry of the β-Mn crystal is defined by mapping the closed icosahedral helix of the {3, 3, 5} polytope into 3D Euclidean space E . This interpretation must be correlated also with the known previous determination of non-crystallographic symmetry of the β-Mn crystal by mapping into the 3D E space system of icosahedra from the 6D cubic B lattice. The recently proposed determination of non-crystallographic symmetry of the β-Mn crystal actually uses the symmetries of the 8D E lattice, in which both the 4D {3, 3, 5} polytope and cubic 6D B lattice can be inserted.
ISSN:2053-2733
2053-2733
DOI:10.1107/S2053273320012978