2-(2,4-Difluorophenyl)-4,5-dimethyl-1-(4-methylphenyl)-1 H -imidazole monohydrate
The asymmetric unit of the title compound, C 18 H 16 F 2 N 2 ·H 2 O, contains two independent molecules ( A and B ), and two independent water molecules of crystallization. In molecule A , the imidazole ring makes dihedral angles of 47.46 (7) and 60.98 (6)° with the 2,4-difluorophenyl and methylphen...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-11, Vol.69 (11), p.o1599-o1600 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The asymmetric unit of the title compound, C
18
H
16
F
2
N
2
·H
2
O, contains two independent molecules (
A
and
B
), and two independent water molecules of crystallization. In molecule
A
, the imidazole ring makes dihedral angles of 47.46 (7) and 60.98 (6)° with the 2,4-difluorophenyl and methylphenyl rings, respectively. The corresponding angles in molecule
B
are 45.85 (7) and 62.78 (7)°, respectively. The dihedral angle between the two benzene rings is 64.98 (7)° in molecule
A
and 65.53 (7)° in molecule
B
. In the crystal, the two independent molecules are linked by O—H...N and O—H...O hydrogen bonds, forming chains propagating along [100]. These chains are linked
via
C—H...F hydrogen bonds, forming slab-like two-dimensional networks lying parallel to (001). |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536813026354 |