Aquabis(4-nitrobenzoato)-κ 2 O , O ′;κ O -(piperidinium-4-carboxylato-κ 2 O , O ′)cadmium(II)
In the mixed ligand title compound, [Cd(C 6 H 11 NO 2 )(C 7 H 4 NO 4 ) 2 (H 2 O)], which exhibits a discrete mononuclear structure, the Cd II atom is in a distorted octahedral geometry, surrounded by five carboxylate O atoms and one coordinated water molecule. The piperdinium ring adopts a chair con...
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| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-06, Vol.65 (6), p.m664-m665 |
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| container_title | Acta crystallographica. Section E, Structure reports online |
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| creator | Zhang, Run-Wen Wang, Li-Li Zhao, Xiao-Jun |
| description | In the mixed ligand title compound, [Cd(C 6 H 11 NO 2 )(C 7 H 4 NO 4 ) 2 (H 2 O)], which exhibits a discrete mononuclear structure, the Cd II atom is in a distorted octahedral geometry, surrounded by five carboxylate O atoms and one coordinated water molecule. The piperdinium ring adopts a chair conformation and the two 4-nitrobenzoate rings are oriented at a dihedral angle of 75.8 (1)°. Intermolecular O—H...O and N—H...O hydrogen bonds link the mononuclear entities into a three-dimensional supramolecular network. |
| doi_str_mv | 10.1107/S160053680901811X |
| format | Article |
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The piperdinium ring adopts a chair conformation and the two 4-nitrobenzoate rings are oriented at a dihedral angle of 75.8 (1)°. Intermolecular O—H...O and N—H...O hydrogen bonds link the mononuclear entities into a three-dimensional supramolecular network.</description><identifier>ISSN: 1600-5368</identifier><identifier>EISSN: 1600-5368</identifier><identifier>DOI: 10.1107/S160053680901811X</identifier><language>eng</language><ispartof>Acta crystallographica. 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Section E, Structure reports online</title><description>In the mixed ligand title compound, [Cd(C 6 H 11 NO 2 )(C 7 H 4 NO 4 ) 2 (H 2 O)], which exhibits a discrete mononuclear structure, the Cd II atom is in a distorted octahedral geometry, surrounded by five carboxylate O atoms and one coordinated water molecule. The piperdinium ring adopts a chair conformation and the two 4-nitrobenzoate rings are oriented at a dihedral angle of 75.8 (1)°. 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Section E, Structure reports online</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Run-Wen</au><au>Wang, Li-Li</au><au>Zhao, Xiao-Jun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Aquabis(4-nitrobenzoato)-κ 2 O , O ′;κ O -(piperidinium-4-carboxylato-κ 2 O , O ′)cadmium(II)</atitle><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle><date>2009-06-01</date><risdate>2009</risdate><volume>65</volume><issue>6</issue><spage>m664</spage><epage>m665</epage><pages>m664-m665</pages><issn>1600-5368</issn><eissn>1600-5368</eissn><abstract>In the mixed ligand title compound, [Cd(C 6 H 11 NO 2 )(C 7 H 4 NO 4 ) 2 (H 2 O)], which exhibits a discrete mononuclear structure, the Cd II atom is in a distorted octahedral geometry, surrounded by five carboxylate O atoms and one coordinated water molecule. The piperdinium ring adopts a chair conformation and the two 4-nitrobenzoate rings are oriented at a dihedral angle of 75.8 (1)°. Intermolecular O—H...O and N—H...O hydrogen bonds link the mononuclear entities into a three-dimensional supramolecular network.</abstract><doi>10.1107/S160053680901811X</doi></addata></record> |
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| source | DOAJ Directory of Open Access Journals; PubMed Central; Free Full-Text Journals in Chemistry; PubMed Central Open Access |
| title | Aquabis(4-nitrobenzoato)-κ 2 O , O ′;κ O -(piperidinium-4-carboxylato-κ 2 O , O ′)cadmium(II) |
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