Aquabis(4-nitrobenzoato)-κ 2 O , O ′;κ O -(piperidinium-4-carboxylato-κ 2 O , O ′)cadmium(II)
In the mixed ligand title compound, [Cd(C 6 H 11 NO 2 )(C 7 H 4 NO 4 ) 2 (H 2 O)], which exhibits a discrete mononuclear structure, the Cd II atom is in a distorted octahedral geometry, surrounded by five carboxylate O atoms and one coordinated water molecule. The piperdinium ring adopts a chair con...
Gespeichert in:
| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-06, Vol.65 (6), p.m664-m665 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | In the mixed ligand title compound, [Cd(C
6
H
11
NO
2
)(C
7
H
4
NO
4
)
2
(H
2
O)], which exhibits a discrete mononuclear structure, the Cd
II
atom is in a distorted octahedral geometry, surrounded by five carboxylate O atoms and one coordinated water molecule. The piperdinium ring adopts a chair conformation and the two 4-nitrobenzoate rings are oriented at a dihedral angle of 75.8 (1)°. Intermolecular O—H...O and N—H...O hydrogen bonds link the mononuclear entities into a three-dimensional supramolecular network. |
|---|---|
| ISSN: | 1600-5368 1600-5368 |
| DOI: | 10.1107/S160053680901811X |