catena -Poly[[bis(thiocyanato-κ N )cobalt(II)]-μ-di-4-pyridylamine-κ 2 N : N ′]

catena -Poly[[bis(thiocyanato-κ N )cobalt(II)]-μ-di-4-pyridylamine-κ 2 N : N ′]

In the title compound, [Co(NCS) 2 (C 10 H 9 N 3 )], a Co II atom with tetrahedral coordination is bound by two N -donor thiocyanate anions and two N -donor atoms from two crystallographically distinct di-4-pyridylamine (dpa) ligands whose central NH units lie on twofold axes. The dpa ligands link th...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2007-11, Vol.63 (11), p.m2705-m2705
Hauptverfasser: Springsteen, Caleb H., LaDuca, Robert L.
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, [Co(NCS) 2 (C 10 H 9 N 3 )], a Co II atom with tetrahedral coordination is bound by two N -donor thiocyanate anions and two N -donor atoms from two crystallographically distinct di-4-pyridylamine (dpa) ligands whose central NH units lie on twofold axes. The dpa ligands link the Co atoms into one-dimensional [Co(NCS) 2 (dpa)] n coordination polymer chains that propagate along the b -axis direction.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536807049276