Chlorido(di‐2‐pyridylamine‐κ2N,N′)(4‐nitrobenzoato‐κ2O,O′)copper(II)

In the title complex, [Cu(C7H4NO4)Cl(C10H9N3)], the Cu atom has a distorted square‐pyramidal geometry defined by one bidentate di‐2‐pyridylamine ligand, one bidentate 4‐nitrobenzoate anion, and a Cl atom in the apical position. The Cu atom deviates from the mean plane of the basal atoms towards the...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2007-08, Vol.63 (8), p.m2162-m2162
Hauptverfasser: Okabe, Nobuo, Tsuji, Akio, Yodoshi, Masahiro
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title complex, [Cu(C7H4NO4)Cl(C10H9N3)], the Cu atom has a distorted square‐pyramidal geometry defined by one bidentate di‐2‐pyridylamine ligand, one bidentate 4‐nitrobenzoate anion, and a Cl atom in the apical position. The Cu atom deviates from the mean plane of the basal atoms towards the Cl atom by 0.3274 (1) Å. The crystal structure is stabilized by N—H...Cl hydrogen bonds and π–π stacking interactions.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536807033776