Diazidobis(2,2′‐biimidazole)nickel(II)

Diazidobis(2,2′‐biimidazole)nickel(II)

Green single crystals of the title compound, [Ni(N3)2(C6H6N4)2], were obtained by reacting nickel(II) perchlorate with 2,2′‐biimidazole (H2bim) and sodium azide. The azide and H2bim ligands are bonded to the Ni atom, which lies on an inversion centre, with approximately octahedral geometry. The azid...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2007-06, Vol.63 (6), p.m1570-m1570
Hauptverfasser: Ni, Zhong‐Hai, Cai, Zhi‐Nan, Zhong, Wei‐Feng, Wei, Shang‐Zheng
Format: Artikel
Sprache:eng
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Zusammenfassung:Green single crystals of the title compound, [Ni(N3)2(C6H6N4)2], were obtained by reacting nickel(II) perchlorate with 2,2′‐biimidazole (H2bim) and sodium azide. The azide and H2bim ligands are bonded to the Ni atom, which lies on an inversion centre, with approximately octahedral geometry. The azide anions are terminally bonded in two trans postitions. A two‐dimensional supramolecular network is formed through hydrogen bonds between ligand H2bim and azide N atoms.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536807021113