Triaqua(pyridine‐2,6‐dicarboxylato)magnesium(II) dihydrate

The reaction of magnesium(II) nitrate hexahydrate with the proton‐transfer compound (pipzH2)(pydc) [pipz is piperazine and pydcH2 is pyridine‐2,6‐dicarboxylic acid] in aqueous solution leads to the formation of the title compound, [Mg(C7H3O4)(H2O)3]·2H2O. The piperazinium cation is not incorporated...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2007-05, Vol.63 (5), p.m1487-m1489
Hauptverfasser: Aghabozorg, Hossein, Ghasemikhah, Pouya, Ghadermazi, Mohammad, Soleimannejad, Janet, Adams, Harry
Format: Artikel
Sprache:eng
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Zusammenfassung:The reaction of magnesium(II) nitrate hexahydrate with the proton‐transfer compound (pipzH2)(pydc) [pipz is piperazine and pydcH2 is pyridine‐2,6‐dicarboxylic acid] in aqueous solution leads to the formation of the title compound, [Mg(C7H3O4)(H2O)3]·2H2O. The piperazinium cation is not incorporated in this crystal structure. The MgII atom has a distorted octahedral coordination environment. There are many intermolecular O—H...O hydrogen bonds involving the (pydc)2− species and water molecules in the crystal structure.
ISSN:1600-5368
1600-5368
DOI:10.1107/S160053680701937X