3‐Deoxy‐1,2‐O‐isopropylidene‐3‐C‐methyl‐5‐O‐(p‐tolylsulfonyl)‐d‐ribofuranose

In the title compound [alternative name: (2,2,6R‐trimethyltetrahydrofuro[2R,3R‐d][1,3]dioxol‐5S‐yl)methyl 4‐methylbenzenesulfonate], C16H22O6S, the ribo‐pentofuranose ring is in the T (twisted) conformation, with atom C3 exo and atom C4 endo. The isopropylidene ring is in an envelope conformation. T...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2007-05, Vol.63 (5), p.o2678-o2680
Hauptverfasser: Novoa de Armas, Hector, Doboszewski, Bogdan, Herdewijn, Piet, Blaton, Norbert
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound [alternative name: (2,2,6R‐trimethyltetrahydrofuro[2R,3R‐d][1,3]dioxol‐5S‐yl)methyl 4‐methylbenzenesulfonate], C16H22O6S, the ribo‐pentofuranose ring is in the T (twisted) conformation, with atom C3 exo and atom C4 endo. The isopropylidene ring is in an envelope conformation. The crystal structure is stabilized by means of van der Waals interactions and weak C—H...O interactions.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536807018624