Dimeric dioxocations, (NpO2+)2, in the structure of bis(μ‐2‐fluorobenzoato‐κ2O:O′)di‐μ‐oxo‐bis[(2,2′‐bipyridine‐κ2N,N′)oxoneptunium(V)]
The centrosymmetric title compound, [(NpO2)2(C7H4FO2)2(C10H8N2)2], contains the dimeric dioxocation (NpO2+)2 in which two of the four O atoms bridge the Np atoms. Two bidentate chelating‐bridging fluorobenzoate anions link the Np atoms of the dimeric cation. The N atoms of the 2,2′‐bipyridine ligan...
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| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2007-02, Vol.63 (2), p.m561-m562 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The centrosymmetric title compound, [(NpO2)2(C7H4FO2)2(C10H8N2)2], contains the dimeric dioxocation (NpO2+)2 in which two of the four O atoms bridge the Np atoms. Two bidentate chelating‐bridging fluorobenzoate anions link the Np atoms of the dimeric cation. The N atoms of the 2,2′‐bipyridine ligand occupy two positions in the equatorial plane of the distorted pentagonal bipyramid, forming a five‐membered metallacycle. |
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| ISSN: | 1600-5368 1600-5368 |
| DOI: | 10.1107/S1600536807002164 |