Aqua(hippurato)bis(1,10‐phenanthroline)manganese(II) perchlorate trihydrate
In the cation of the title compound, [Mn(C9H7NO3)(C12H10N2)2(H2O)]ClO4·3H2O, the MnII atom is coordinated by two O atoms, one from a hippurate ligand and the other from a coordinated water molecule, and four N atoms from two 1,10‐phenanthroline ligands. In the crystal structure, the cations and wat...
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| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2006-10, Vol.62 (10), p.m2706-m2708 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | In the cation of the title compound, [Mn(C9H7NO3)(C12H10N2)2(H2O)]ClO4·3H2O, the MnII atom is coordinated by two O atoms, one from a hippurate ligand and the other from a coordinated water molecule, and four N atoms from two 1,10‐phenanthroline ligands. In the crystal structure, the cations and water molecules are linked by intra‐ and intermolecular hydrogen bonds, forming R64(12) rings; these rings are further connected by intermolecular hydrogen bonds and C—H⋯π interactions into a three‐dimensional supramolecular framework. |
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| ISSN: | 1600-5368 1600-5368 |
| DOI: | 10.1107/S1600536806038177 |