catena‐Poly[[diaquapyridinecadmium(II)]‐μ‐terephthalato]
The title compound, [Cd(C8H4O4)(C5H5N)(H2O)2]n, is a one‐dimensional spiral polymer in which the organic species act in bis‐monodentate and bis‐bidentate coordination modes. The two crystallographically independent terephthalate ligands lie on centers of symmetry. The Cd2+ cation is hexacoordinated...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2006-09, Vol.62 (9), p.m2054-m2056 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The title compound, [Cd(C8H4O4)(C5H5N)(H2O)2]n, is a one‐dimensional spiral polymer in which the organic species act in bis‐monodentate and bis‐bidentate coordination modes. The two crystallographically independent terephthalate ligands lie on centers of symmetry. The Cd2+ cation is hexacoordinated in a distorted octahedral geometry by five O atoms [Cd—O = 2.2370 (16)–2.4928 (17) Å] and one N atom [Cd—N = 2.316 (2) Å]. The water molecules and carboxylate O atoms are involved in O—H⋯O hydrogen bonds, which link adjacent polymeric chains into a three‐dimensional supramolecular network. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S160053680603008X |