catena‐Poly[[diaqua­pyridine­cadmium(II)]‐μ‐terephthalato]

The title compound, [Cd(C8H4O4)(C5H5N)(H2O)2]n, is a one‐dimensional spiral polymer in which the organic species act in bis‐monodentate and bis‐bidentate coordination modes. The two crystallographically independent terephthalate ligands lie on centers of symmetry. The Cd2+ cation is hexa­coordinated...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2006-09, Vol.62 (9), p.m2054-m2056
Hauptverfasser: Ni, Qing‐Ling, Li, Fa‐Si, Bi, Xian‐Shu, Wang, Xiu‐Jian, Gui, Liu‐Chen
Format: Artikel
Sprache:eng
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Zusammenfassung:The title compound, [Cd(C8H4O4)(C5H5N)(H2O)2]n, is a one‐dimensional spiral polymer in which the organic species act in bis‐monodentate and bis‐bidentate coordination modes. The two crystallographically independent terephthalate ligands lie on centers of symmetry. The Cd2+ cation is hexa­coordinated in a distorted octa­hedral geometry by five O atoms [Cd—O = 2.2370 (16)–2.4928 (17) Å] and one N atom [Cd—N = 2.316 (2) Å]. The water mol­ecules and carboxyl­ate O atoms are involved in O—H⋯O hydrogen bonds, which link adjacent polymeric chains into a three‐dimensional supra­molecular network.
ISSN:1600-5368
1600-5368
DOI:10.1107/S160053680603008X