4,4′-Bis(2,6-dichlorobenzylideneamino)biphenyl

The title molecule, C 26 H 16 Cl 4 N 2 , lies on a crystallographic inversion centre and is disordered. The dihedral angle between the two benzene rings of the central biphenyl unit is 34.4 (3)°. The unique benzene ring of the biphenyl group is essentially coplanar with the –C(H)=N– unit, whereas th...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2006-05, Vol.62 (5), p.o1901-o1902
Hauptverfasser: Hou, Zhen-Yu, Zhu, Dong-Mei, Ng, Seik Weng
Format: Artikel
Sprache:eng
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Zusammenfassung:The title molecule, C 26 H 16 Cl 4 N 2 , lies on a crystallographic inversion centre and is disordered. The dihedral angle between the two benzene rings of the central biphenyl unit is 34.4 (3)°. The unique benzene ring of the biphenyl group is essentially coplanar with the –C(H)=N– unit, whereas the 2,6-dichlorophenyl substituent is twisted with respect to it. The reason for the twisted conformation is attributed to steric crowding by the Cl atoms.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536806013092