4,4′-Bis(2,6-dichlorobenzylideneamino)biphenyl
The title molecule, C 26 H 16 Cl 4 N 2 , lies on a crystallographic inversion centre and is disordered. The dihedral angle between the two benzene rings of the central biphenyl unit is 34.4 (3)°. The unique benzene ring of the biphenyl group is essentially coplanar with the –C(H)=N– unit, whereas th...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2006-05, Vol.62 (5), p.o1901-o1902 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The title molecule, C
26
H
16
Cl
4
N
2
, lies on a crystallographic inversion centre and is disordered. The dihedral angle between the two benzene rings of the central biphenyl unit is 34.4 (3)°. The unique benzene ring of the biphenyl group is essentially coplanar with the –C(H)=N– unit, whereas the 2,6-dichlorophenyl substituent is twisted with respect to it. The reason for the twisted conformation is attributed to steric crowding by the Cl atoms. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536806013092 |