Diaquasulfato(2,4,6-tri-2-pyridyl-1,3,5-triazine)nickel(II) dihydrate
The title compound, [Ni(SO 4 )(C 18 H 12 N 6 )(H 2 O) 2 ]·2H 2 O, is isostructural with the zinc and cobalt analogues already reported in the literature. The compound is monomeric, with an octahedral Ni centre coordinated by a tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand, two water molecules...
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| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2006-05, Vol.62 (5), p.m986-m988 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The title compound, [Ni(SO
4
)(C
18
H
12
N
6
)(H
2
O)
2
]·2H
2
O, is isostructural with the zinc and cobalt analogues already reported in the literature. The compound is monomeric, with an octahedral Ni centre coordinated by a tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand, two water molecules and a monodentate sulfate ligand. The presence of two additional water molecules of crystallization leads to a total of eight hydrogen-bond donors, from which a very complex hydrogen-bonding scheme is built up. |
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| ISSN: | 1600-5368 1600-5368 |
| DOI: | 10.1107/S1600536806011640 |