catena‐Poly[cadmium(II)‐di‐μ‐N‐oxopyridine‐2‐thiol­ato]

catena‐Poly[cadmium(II)‐di‐μ‐N‐oxopyridine‐2‐thiol­ato]

In the title complex, [Cd(C5H4NOS)2]n, (I), the Cd atom is located on an inversion center and is coordinated by two S [Cd—S = 2.5225 (6) Å] and four O [Cd—O = 2.3931 (16) and 2.5543 (17) Å] atoms in a distorted octa­hedral geometry. Two N‐oxopyridine‐2‐thiol­ate (PySO) ligands chelate the Cd atom to...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2006-04, Vol.62 (4), p.m931-m933
Hauptverfasser: Wang, Xiu‐Jian, Gui, Liu‐Chen, Shen, Zhong‐Su, Ni, Qing‐Ling, Zeng, Jian‐Qiang
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title complex, [Cd(C5H4NOS)2]n, (I), the Cd atom is located on an inversion center and is coordinated by two S [Cd—S = 2.5225 (6) Å] and four O [Cd—O = 2.3931 (16) and 2.5543 (17) Å] atoms in a distorted octa­hedral geometry. Two N‐oxopyridine‐2‐thiol­ate (PySO) ligands chelate the Cd atom to occupy four sites of the equatorial plane, while two O atoms from another two PySO ligands occupy the axial sites. PySO acts as a bridging chelating ligand (S‐μ2‐O), connecting adjacent Cd atoms to form a polymeric chain.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536806010841