Chloro­(pyrimidine‐2‐thiol­ato‐κ2N,S)(triphenyl­phosphine‐κP)palladium(II) methanol hemisolvate

Chloro­(pyrimidine‐2‐thiol­ato‐κ2N,S)(triphenyl­phosphine‐κP)palladium(II) methanol hemisolvate

In the title compound, [Pd(C4H3N2S)Cl(C18H15P)]·0.5CH3OH, the Pd atom is four‐coordinate and exhibits a slightly distorted square‐planar geometry with the S atom of the pyrimidine‐2‐thiol­ate ligand trans to the chloro ligand and the coordinated N atom trans to the phosphine. The compound crystalliz...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2006-01, Vol.62 (1), p.m138-m140
Hauptverfasser: Shaheen, Farkhanda, Najam‐Ul‐Haq, Muhammad, Wurst, Klaus, Ali, Saqib, Badshah, Amin
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, [Pd(C4H3N2S)Cl(C18H15P)]·0.5CH3OH, the Pd atom is four‐coordinate and exhibits a slightly distorted square‐planar geometry with the S atom of the pyrimidine‐2‐thiol­ate ligand trans to the chloro ligand and the coordinated N atom trans to the phosphine. The compound crystallizes with two unique mol­ecules and a disordered methanol solvent mol­ecule in the asymmetric unit.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536805041681