Dipotassium ethane‐1,1‐diylbis(diazeniumdiolate) monohydrate
The ethane‐1,1‐bis(diazeniumdiolate) anion in the title compound, 2K+·C2H4N4O42−·H2O, acts as a complex bridging ligand. Both the N and the O atoms of the diazeniumdiolate substituents are coordinated to the K+ cations, revealing the delocalization of a negative charge over the four‐atom groups....
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| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2005-04, Vol.61 (4), p.m764-m766 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The ethane‐1,1‐bis(diazeniumdiolate) anion in the title compound, 2K+·C2H4N4O42−·H2O, acts as a complex bridging ligand. Both the N and the O atoms of the diazeniumdiolate substituents are coordinated to the K+ cations, revealing the delocalization of a negative charge over the four‐atom groups. |
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| ISSN: | 1600-5368 1600-5368 |
| DOI: | 10.1107/S1600536805008822 |