Aurophilic and hydrogen‐bonding interactions in [1‐(diphenyl­phosphino)‐4‐(diphenyl­phos­phin­oyl)­butane‐κP1]iodogold(I) monohydrate

Aurophilic and hydrogen‐bonding interactions in [1‐(diphenyl­phosphino)‐4‐(diphenyl­phos­phin­oyl)­butane‐κP1]iodogold(I) monohydrate

In the title compound, [AuI(C28H28OP2)]·H2O, the 1‐(di­phenyl­phosphino)‐4‐(diphenyl­phosphinoyl)butane (dppbO) ligand coordinates through the phospho­rus donor to give a linear two‐coordinate P—Au—I gold(I) complex. Pairs of [AuI(dppbO)] molecules are linked by symmetric tris‐water hydrogen‐bond in...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2005-01, Vol.61 (1), p.m30-m32
Hauptverfasser: Williams, Michael L., Slade, Deborah L., Boyd, Sue E., Healy, Peter C.
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, [AuI(C28H28OP2)]·H2O, the 1‐(di­phenyl­phosphino)‐4‐(diphenyl­phosphinoyl)butane (dppbO) ligand coordinates through the phospho­rus donor to give a linear two‐coordinate P—Au—I gold(I) complex. Pairs of [AuI(dppbO)] molecules are linked by symmetric tris‐water hydrogen‐bond interactions. These dimers associate in zigzag fashion through intermolecular Au⋯Au interactions between mutually perpendicular P—Au—I groups.
ISSN:1600-5368
1600-5368
DOI:10.1107/S160053680403137X