Bis­(tetra­phenyl­phospho­nium) bis­(tetra­seleno­molybdato)­palladate(II)

Bis­(tetra­phenyl­phospho­nium) bis­(tetra­seleno­molybdato)­palladate(II)

In the title compound, (C24H20P)2[Pd(MoSe4)2], the [Pd(MoSe4)2]2− anion has the PdII atom on a crystallographic inversion center with distorted square‐planar geometry, coordinated by two nearly tetra­hedral bidentate MoSe42− ligands. It is the first complex of palladium and tetra­seleno­molybdate to...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2004-10, Vol.60 (10), p.m1539-m1541
Hauptverfasser: Shiffler, Zachary J., Baldwin, Steven M., Keane, Joseph M., Belz, Brian L., Barr, Matthew L., Slavin, Edward R., Kastner, Margaret E., Mahler, Charles H.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:In the title compound, (C24H20P)2[Pd(MoSe4)2], the [Pd(MoSe4)2]2− anion has the PdII atom on a crystallographic inversion center with distorted square‐planar geometry, coordinated by two nearly tetra­hedral bidentate MoSe42− ligands. It is the first complex of palladium and tetra­seleno­molybdate to be structurally characterized.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536804023104