(η8‐Cyclooctatetraenyl)(m‐terphenyl)lutetium‐μ‐chloro‐[tris(tetrahydrofuran)lithium(I)]
The molecular structure of a mixed terphenyl COT compound (COT is cyclooctatetraene) of the element lutetium, of composition DppLuCOT(μ‐Cl)Li(THF)3 (Dpp is 2,6‐diphenylphenyl, or m‐terphenyl, and THF is tetrahydrofuran) or [LuLi(C8H8)(C18H13)Cl(C4H8O)3], is reported. The monomeric complex cont...
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| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2004-10, Vol.60 (10), p.m1389-m1390 |
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| container_title | Acta crystallographica. Section E, Structure reports online |
| container_volume | 60 |
| creator | Rabe, Gerd W. Zhang‐Preße, Mei Riederer, Florian A. Incarvito, Christopher D. Golen, James A. Rheingold, Arnold L. |
| description | The molecular structure of a mixed terphenyl COT compound (COT is cyclooctatetraene) of the element lutetium, of composition DppLuCOT(μ‐Cl)Li(THF)3 (Dpp is 2,6‐diphenylphenyl, or m‐terphenyl, and THF is tetrahydrofuran) or [LuLi(C8H8)(C18H13)Cl(C4H8O)3], is reported. The monomeric complex contains one η8‐bonded COT and one σ‐bonded terphenyl ligand, as well as a lithium chloride moiety, with the alkali metal atom solvated by three tetrahydrofuran molecules. |
| doi_str_mv | 10.1107/S1600536804021439 |
| format | Article |
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The monomeric complex contains one η8‐bonded COT and one σ‐bonded terphenyl ligand, as well as a lithium chloride moiety, with the alkali metal atom solvated by three tetrahydrofuran molecules.</description><identifier>ISSN: 1600-5368</identifier><identifier>EISSN: 1600-5368</identifier><identifier>DOI: 10.1107/S1600536804021439</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: Munksgaard International Publishers</publisher><ispartof>Acta crystallographica. 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Section E, Structure reports online</title><description>The molecular structure of a mixed terphenyl COT compound (COT is cyclooctatetraene) of the element lutetium, of composition DppLuCOT(μ‐Cl)Li(THF)3 (Dpp is 2,6‐diphenylphenyl, or m‐terphenyl, and THF is tetrahydrofuran) or [LuLi(C8H8)(C18H13)Cl(C4H8O)3], is reported. The monomeric complex contains one η8‐bonded COT and one σ‐bonded terphenyl ligand, as well as a lithium chloride moiety, with the alkali metal atom solvated by three tetrahydrofuran molecules.</description><issn>1600-5368</issn><issn>1600-5368</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqFkE9Kw0AUxgdRsFYP4A3SRfRN_kw6yxqqFgourAsRCdM3MySSNmWSINl5BC-StRtXOUAP4UmctC4EF27en-_j9-B9hJxTuKAUost7ygBCn40hAI8GPj8gg15ye-3w13xMTsryBYCyyKMDsnK2H-Ovt_e4wbwosBKVqoxQ6yYfOSurV8p07SbdCV2b19bO6t7YftqCaV6Ywg5PlcnKrnV2dNpIU3Stro1Y91BWpZZxZqPnU3KkRV6qs58-JA_X00V8687vbmbxZO6iR4G7UnvaE37oSx1KoAoZ1xRDEEyEgPZfCiiCcRQBD1AiaibswpZLiVKFAP6Q0P1dNEVZGqWTjclWwjQJhaTPK_mTl2X4nnnNctX8DySTx6l3tWAB5_43UUt6Vg</recordid><startdate>200410</startdate><enddate>200410</enddate><creator>Rabe, Gerd W.</creator><creator>Zhang‐Preße, Mei</creator><creator>Riederer, Florian A.</creator><creator>Incarvito, Christopher D.</creator><creator>Golen, James A.</creator><creator>Rheingold, Arnold L.</creator><general>Munksgaard International Publishers</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200410</creationdate><title>(η8‐Cyclooctatetraenyl)(m‐terphenyl)lutetium‐μ‐chloro‐[tris(tetrahydrofuran)lithium(I)]</title><author>Rabe, Gerd W. ; Zhang‐Preße, Mei ; Riederer, Florian A. ; Incarvito, Christopher D. ; Golen, James A. ; Rheingold, Arnold L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2109-df2f2a353df5d01ec69f1c50a6a50c11010ca4877094cdccf6a8776bbdcde5003</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Rabe, Gerd W.</creatorcontrib><creatorcontrib>Zhang‐Preße, Mei</creatorcontrib><creatorcontrib>Riederer, Florian A.</creatorcontrib><creatorcontrib>Incarvito, Christopher D.</creatorcontrib><creatorcontrib>Golen, James A.</creatorcontrib><creatorcontrib>Rheingold, Arnold L.</creatorcontrib><collection>CrossRef</collection><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rabe, Gerd W.</au><au>Zhang‐Preße, Mei</au><au>Riederer, Florian A.</au><au>Incarvito, Christopher D.</au><au>Golen, James A.</au><au>Rheingold, Arnold L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>(η8‐Cyclooctatetraenyl)(m‐terphenyl)lutetium‐μ‐chloro‐[tris(tetrahydrofuran)lithium(I)]</atitle><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle><date>2004-10</date><risdate>2004</risdate><volume>60</volume><issue>10</issue><spage>m1389</spage><epage>m1390</epage><pages>m1389-m1390</pages><issn>1600-5368</issn><eissn>1600-5368</eissn><abstract>The molecular structure of a mixed terphenyl COT compound (COT is cyclooctatetraene) of the element lutetium, of composition DppLuCOT(μ‐Cl)Li(THF)3 (Dpp is 2,6‐diphenylphenyl, or m‐terphenyl, and THF is tetrahydrofuran) or [LuLi(C8H8)(C18H13)Cl(C4H8O)3], is reported. The monomeric complex contains one η8‐bonded COT and one σ‐bonded terphenyl ligand, as well as a lithium chloride moiety, with the alkali metal atom solvated by three tetrahydrofuran molecules.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>Munksgaard International Publishers</pub><doi>10.1107/S1600536804021439</doi></addata></record> |
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| source | Wiley Journals; Free Full-Text Journals in Chemistry |
| title | (η8‐Cyclooctatetraenyl)(m‐terphenyl)lutetium‐μ‐chloro‐[tris(tetrahydrofuran)lithium(I)] |
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