(η8‐Cyclooctatetraenyl)(m‐ter­phenyl)­lutetium‐μ‐chloro‐[tris­(tetrahydro­furan)­lithium(I)]

(η8‐Cyclooctatetraenyl)(m‐ter­phenyl)­lutetium‐μ‐chloro‐[tris­(tetrahydro­furan)­lithium(I)]

The molecular structure of a mixed ter­phenyl COT compound (COT is cyclo­octatetraene) of the element lutetium, of composition DppLuCOT(μ‐Cl)Li(THF)3 (Dpp is 2,6‐di­phenyl­phenyl, or m‐terphenyl, and THF is tetra­hydro­furan) or [LuLi(C8H8)(C18H13)Cl(C4H8O)3], is reported. The monomeric complex cont...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2004-10, Vol.60 (10), p.m1389-m1390
Hauptverfasser: Rabe, Gerd W., Zhang‐Preße, Mei, Riederer, Florian A., Incarvito, Christopher D., Golen, James A., Rheingold, Arnold L.
Format: Artikel
Sprache:eng
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Zusammenfassung:The molecular structure of a mixed ter­phenyl COT compound (COT is cyclo­octatetraene) of the element lutetium, of composition DppLuCOT(μ‐Cl)Li(THF)3 (Dpp is 2,6‐di­phenyl­phenyl, or m‐terphenyl, and THF is tetra­hydro­furan) or [LuLi(C8H8)(C18H13)Cl(C4H8O)3], is reported. The monomeric complex contains one η8‐bonded COT and one σ‐bonded ter­phenyl ligand, as well as a lithium chloride moiety, with the alkali metal atom solvated by three tetra­hydro­furan mol­ecules.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536804021439