(1,4,7,10,13,16‐Hexaoxa­cyclo­octa­decane)­potassium dithiocyanatoaurate(I)

(1,4,7,10,13,16‐Hexaoxa­cyclo­octa­decane)­potassium dithiocyanatoaurate(I)

In the title compound, [K(C12H24O6)][Au(SCN)2], the AuI atom is in a linear configuration with respect to the coordinating S atoms. The encapsulation of the K+ ion by the 18‐crown‐6 ligand produces a large cation and prevents Au⃛Au interactions within the extended structure. Both Au and K occupy inv...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2004-06, Vol.60 (6), p.m814-m816
Hauptverfasser: Coker, Nathan L., Krause Bauer, Jeanette A., Elder, R. C.
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, [K(C12H24O6)][Au(SCN)2], the AuI atom is in a linear configuration with respect to the coordinating S atoms. The encapsulation of the K+ ion by the 18‐crown‐6 ligand produces a large cation and prevents Au⃛Au interactions within the extended structure. Both Au and K occupy inversion centers.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536804011614