(S)‐2‐(Methoxy­di­phenyl­methyl)‐1‐(thio­phen‐3‐yl­methyl)­pyrrolidine

The crystal and molecular structure of the title compound, C23H25NOS, has been determined by means of X‐ray diffraction. This compound is readily li­thia­ted with n‐butyl­lithium at the 2‐position of the thio­phene ring to give a chiral li­thio­thio­phene that can be used as a chiral template for en...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2003-12, Vol.59 (12), p.o1970-o1971
Hauptverfasser: Martin, Erica, Winfrey, A. Leigh, Human, Jason B., Carlin, C. Zachary, Jones, Daniel S., Ogle, Craig A.
Format: Artikel
Sprache:eng
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Zusammenfassung:The crystal and molecular structure of the title compound, C23H25NOS, has been determined by means of X‐ray diffraction. This compound is readily li­thia­ted with n‐butyl­lithium at the 2‐position of the thio­phene ring to give a chiral li­thio­thio­phene that can be used as a chiral template for enantioselective conjugate addition of an alkyl group to an enone.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536803026035