(S)‐2‐(Methoxydiphenylmethyl)‐1‐(thiophen‐3‐ylmethyl)pyrrolidine
The crystal and molecular structure of the title compound, C23H25NOS, has been determined by means of X‐ray diffraction. This compound is readily lithiated with n‐butyllithium at the 2‐position of the thiophene ring to give a chiral lithiothiophene that can be used as a chiral template for en...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2003-12, Vol.59 (12), p.o1970-o1971 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The crystal and molecular structure of the title compound, C23H25NOS, has been determined by means of X‐ray diffraction. This compound is readily lithiated with n‐butyllithium at the 2‐position of the thiophene ring to give a chiral lithiothiophene that can be used as a chiral template for enantioselective conjugate addition of an alkyl group to an enone. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536803026035 |