(Acetyl­acetonato)­carbonyl­[di­allyl(tert‐butyl)­phosphine]­rhodium(I)

(Acetyl­acetonato)­carbonyl­[di­allyl(tert‐butyl)­phosphine]­rhodium(I)

The crystal structure of the title compound, [Rh(C5H7O2)(C10H19P)(CO)], consists of discrete chiral mol­ecules. The square‐planar coordination geometry around RhI involves two O atoms of one acetyl­acetonate ligand, one carbonyl group and one P atom of a monodentate di­allyl­phosphine. The double bo...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2003-08, Vol.59 (8), p.m633-m635
Hauptverfasser: Ocando‐Mavarez, Edgar, Ascanio, Julián, González, Teresa, Atencio, Reinaldo, Rosales, Merlín, Silva, Ninoska
Format: Artikel
Sprache:eng
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Zusammenfassung:The crystal structure of the title compound, [Rh(C5H7O2)(C10H19P)(CO)], consists of discrete chiral mol­ecules. The square‐planar coordination geometry around RhI involves two O atoms of one acetyl­acetonate ligand, one carbonyl group and one P atom of a monodentate di­allyl­phosphine. The double bonds of the allyl groups have a mutual π–π interaction.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536803015691