Bis(μ‐N‐methyl‐N‐phenyldithiocarbamato)[bis(N‐methyl‐N‐phenyldithiocarbamato)zinc(II)]
The Zn atom in the centrosymmetric title compound, [Zn2(C8H8NS2)4], is almost symmetrically coordinated by one terminal bidentate N‐phenyl‐N‐methyldithiocarbamate ligand [Zn—S 2.348 (1) and 2.459 (1) Å] and non‐symmetrically coordinated by a second bidentate bridging dithiocarbamate ligand [Zn—...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2002-12, Vol.58 (12), p.m744-m745 |
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Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The Zn atom in the centrosymmetric title compound, [Zn2(C8H8NS2)4], is almost symmetrically coordinated by one terminal bidentate N‐phenyl‐N‐methyldithiocarbamate ligand [Zn—S 2.348 (1) and 2.459 (1) Å] and non‐symmetrically coordinated by a second bidentate bridging dithiocarbamate ligand [Zn—S 2.316 (1) and 2.980 (1) Å]. The latter also uses its bridging S atom to coordinate the second Zn atom [Zn—S 2.378 (1) Å], thus forming a dimeric binuclear complex. Taking into account the long Zn⋯S distance, the Zn atom has a distorted trigonal–bipyramidal coordination. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536802021141 |