Bis(μ‐N‐methyl‐N‐phenyl­di­thio­carbamato)[bis(N‐methyl‐N‐phenyl­di­thio­carbamato)­zinc(II)]

The Zn atom in the centrosymmetric title compound, [Zn2(C8H8NS2)4], is almost symmetrically coordinated by one terminal bidentate N‐phenyl‐N‐methyl­di­thio­carbamate ligand [Zn—S 2.348 (1) and 2.459 (1) Å] and non‐symmetrically coordinated by a second bidentate bridging di­thio­carbamate ligand [Zn—...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2002-12, Vol.58 (12), p.m744-m745
Hauptverfasser: Baba, Ibrahim, Lee, Lay Hoon, Farina, Yang, Othman, A. Hamid, Ibrahim, Abdul Razak, Usman, Awang, Fun, Hoong‐Kun, Ng, Seik Weng
Format: Artikel
Sprache:eng
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Zusammenfassung:The Zn atom in the centrosymmetric title compound, [Zn2(C8H8NS2)4], is almost symmetrically coordinated by one terminal bidentate N‐phenyl‐N‐methyl­di­thio­carbamate ligand [Zn—S 2.348 (1) and 2.459 (1) Å] and non‐symmetrically coordinated by a second bidentate bridging di­thio­carbamate ligand [Zn—S 2.316 (1) and 2.980 (1) Å]. The latter also uses its bridging S atom to coordinate the second Zn atom [Zn—S 2.378 (1) Å], thus forming a dimeric binuclear complex. Taking into account the long Zn⋯S distance, the Zn atom has a distorted trigonal–bipyramidal coordination.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536802021141