R , R -(+)-Bis[(3-benzyloxazolan-4-yl)methyl] disulfide

R , R -(+)-Bis[(3-benzyloxazolan-4-yl)methyl] disulfide

R,R -Bis[(3-benzyloxazolan-4-yl)-methyl] disulfide, C 22 H 28 N 2 O 2 S 2 , is a chiral disulfide which is a highly effective catalyst for the enantioselective addition of diethylzinc to aldehydes, including aliphatic ones. The molecule has crystallographic twofold rotation symmetry.

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2001-01, Vol.57 (1), p.o41-o42
Hauptverfasser: Schulz Lang, Ernesto, Burrow, Robert A., Braga, Antonio Luiz, Appelt, Helmoz Roseniaim, Schneider, Paulo Henrique, Silveira, Claudio Cruz, Wessjohann, Ludger A.
Format: Artikel
Sprache:eng
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Zusammenfassung:R,R -Bis[(3-benzyloxazolan-4-yl)-methyl] disulfide, C 22 H 28 N 2 O 2 S 2 , is a chiral disulfide which is a highly effective catalyst for the enantioselective addition of diethylzinc to aldehydes, including aliphatic ones. The molecule has crystallographic twofold rotation symmetry.
ISSN:1600-5368
1600-5368
DOI:10.1107/S160053680001878X