Magnetic behaviour of synthetic Co 2 SiO 4

Synthetic Co 2 SiO 4 crystallizes in the olivine structure (space group Pnma) with two crystallographically non-equivalent Co positions and shows antiferromagnetic ordering below 50 K. We have investigated the temperature variation of the Co 2 SiO 4 magnetic structure by means of non-polarized and p...

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Veröffentlicht in:Acta crystallographica. Section B, Structural science Structural science, 2009-12, Vol.65 (6), p.664-675
Hauptverfasser: Sazonov, Andrew, Meven, Martin, Hutanu, Vladimir, Heger, Gernot, Hansen, Thomas, Gukasov, Arsen
Format: Artikel
Sprache:eng
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Zusammenfassung:Synthetic Co 2 SiO 4 crystallizes in the olivine structure (space group Pnma) with two crystallographically non-equivalent Co positions and shows antiferromagnetic ordering below 50 K. We have investigated the temperature variation of the Co 2 SiO 4 magnetic structure by means of non-polarized and polarized neutron diffraction for single crystals. Measurements with non-polarized neutrons were made at 2.5 K (below T N ), whereas polarized neutron diffraction experiments were carried out at 70 and 150 K (above T N ) in an external magnetic field of 7 T parallel to the b axis. Additional accurate non-polarized powder diffraction studies were performed in a broad temperature range from 5 to 500 K with small temperature increments. Detailed symmetry analysis of the Co 2 SiO 4 magnetic structure shows that it corresponds to the magnetic (Shubnikov) group Pnma , which allows the antiferromagnetic configuration ( G x , C y , A z ) for the 4 a site with inversion symmetry \bar{1} (Co1 position) and (0, C y ,0) for the 4 c site with mirror symmetry m (Co2 position). The temperature dependence of the Co1 and Co2 magnetic moments obtained from neutron diffraction experiments was fitted in a modified molecular-field model. The polarized neutron study of the magnetization induced by an applied field shows a non-negligible amount of magnetic moment on the oxygen positions, indicating a delocalization of the magnetic moment from Co towards neighbouring O owing to superexchange coupling. The relative strength of the exchange interactions is discussed based on the non-polarized and polarized neutron data.
ISSN:0108-7681
DOI:10.1107/S0108768109042499