Chloro(η6-p-cymene)(2-methyl-5-oxo-7-phenyl-5,6-di­hydro-2H-1,2,4-triaz­epine-3-thiol­ato-κ2N4,S)­ruthenium(II)

Chloro(η6-p-cymene)(2-methyl-5-oxo-7-phenyl-5,6-di­hydro-2H-1,2,4-triaz­epine-3-thiol­ato-κ2N4,S)­ruthenium(II)

The novel title ruthenium(II) complex, [RuCl(C10H14)(C10H10N3OS)], was synthesized from the reaction of 1,2,4‐triazepine, a new class of bidentate ligands, with [Ru(p‐cymene)Cl2]2. The 1,2,4‐triazepine ligand is coordinated to the metal centre through the N‐4 and S atoms, forming a four‐membered che...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2000-08, Vol.56 (8), p.e315-e316
Hauptverfasser: Aitali, Mustapha, Ait Itto, My Youssef, Hasnaoui, Aisa, Riahi, Abdelkhalek, Karim, Abdellah, García-Granda, Santiago, Gutiérrez-Rodríguez, Angel
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Sprache:eng
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Zusammenfassung:The novel title ruthenium(II) complex, [RuCl(C10H14)(C10H10N3OS)], was synthesized from the reaction of 1,2,4‐triazepine, a new class of bidentate ligands, with [Ru(p‐cymene)Cl2]2. The 1,2,4‐triazepine ligand is coordinated to the metal centre through the N‐4 and S atoms, forming a four‐membered chelate ring. This is the first structural example of a transition metal complex containing a 1,2,4‐triazepine ligand.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270100008891