Microphase Ordering in Melts of Randomly Grafted Copolymers

Using optical birefringence, small-angle neutron scattering, and field-theoretic methods, we study the effects of frustrating quenched randomness and connectivity on microphase ordering in copolymer melts. Our results show that randomly grafted copolymers are good model systems to examine these effe...

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Veröffentlicht in:Physical Review Letters 1999-04, Vol.82 (14), p.2896-2899
Hauptverfasser: Qi, Shuyan, Chakraborty, Arup K., Wang, Hao, Lefebvre, Amy A., Balsara, Nitash P., Shakhnovich, Eugene I., Xenidou, Maria, Hadjichristidis, Nikos
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Sprache:eng
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Zusammenfassung:Using optical birefringence, small-angle neutron scattering, and field-theoretic methods, we study the effects of frustrating quenched randomness and connectivity on microphase ordering in copolymer melts. Our results show that randomly grafted copolymers are good model systems to examine these effects, and we find that these materials exhibit behavior different from that observed heretofore for other types of molten polymers. {copyright} {ital 1999} {ital The American Physical Society}
ISSN:0031-9007
1079-7114
DOI:10.1103/PhysRevLett.82.2896