Metallic resistivity in crystalline ropes of single-wall carbon nanotubes

Laser ablation of (Co,Ni)-doped graphite yields {approximately} 70{percent} single-wall nanotubes, predominantly (10,10) armchair tubes which self-organize into crystalline {open_quotes}ropes{close_quotes}{gt}100 {Angstrom} in diameter and{gt}10 {mu}m long. We find {rho}{sub {parallel}}=0.03{minus}0...

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Veröffentlicht in:Physical Review, B: Condensed Matter B: Condensed Matter, 1997-02, Vol.55 (8), p.R4921-R4924
Hauptverfasser: Fischer, J. E., Dai, H., Thess, A., Lee, R., Hanjani, N. M., Dehaas, D. L., Smalley, R. E.
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Sprache:eng
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Zusammenfassung:Laser ablation of (Co,Ni)-doped graphite yields {approximately} 70{percent} single-wall nanotubes, predominantly (10,10) armchair tubes which self-organize into crystalline {open_quotes}ropes{close_quotes}{gt}100 {Angstrom} in diameter and{gt}10 {mu}m long. We find {rho}{sub {parallel}}=0.03{minus}0.10m{Omega} cm at 300 K, with positive (negative) d{rho}/dT above (below) T{sup {asterisk}} = 35 K. Unoriented bulk samples exhibit similar behavior, with higher (directionally averaged) resistivities and T{sup {asterisk}}`s. The high-T behavior is consistent with the predicted intrinsic metallic state for this structure. {copyright} {ital 1997} {ital The American Physical Society}
ISSN:0163-1829
1095-3795
DOI:10.1103/PhysRevB.55.R4921