New synthetic routes for quantum dots

Various methods for the synthesis of quantum dots of compound semiconductors are discussed. Emphasis is placed on methods involving the decomposition of chalcogenide-containing precursors in tri-n-octylphosphine oxide. The use of simple coordination complexes can avoid the use of pyrophoric precurso...

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Veröffentlicht in:Philosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences physical, and engineering sciences, 2003-02, Vol.361 (1803), p.297-310
Hauptverfasser: Crouch, David, Norager, Sebastian, O'Brien, Paul, Park, Jin-Ho, Pickett, Nigel
Format: Artikel
Sprache:eng
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Zusammenfassung:Various methods for the synthesis of quantum dots of compound semiconductors are discussed. Emphasis is placed on methods involving the decomposition of chalcogenide-containing precursors in tri-n-octylphosphine oxide. The use of simple coordination complexes can avoid the use of pyrophoric precursors. Approaches based on melts or the use of imino-bisdichalcogeno-diphosphinates are also discussed. These routes may be suitable for the production of large quantities of quantum dots.
ISSN:1364-503X
1471-2962
DOI:10.1098/rsta.2002.1129