Configuration Interaction Effect on Diamagnetic Phenomena in Atoms: Strong Mixing and Landau Regions

We present a systematic densitometer mapping of diamagnetic effects on the principal series of Ba and Sr in absorption, with magnetic fields up to 4.7 T. The n- and l-mixing spectra are resolved in both σ- and π-polarization while the quasi-Landau resonances are observed near and above the ionizatio...

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Veröffentlicht in:Proceedings of the Royal Society of London. Series A, Mathematical and physical sciences Mathematical and physical sciences, 1978-08, Vol.362 (1710), p.421-424
Hauptverfasser: Lu, K. T., Tomkins, F. S., Garton, William Reginald Stephen
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Sprache:eng
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Zusammenfassung:We present a systematic densitometer mapping of diamagnetic effects on the principal series of Ba and Sr in absorption, with magnetic fields up to 4.7 T. The n- and l-mixing spectra are resolved in both σ- and π-polarization while the quasi-Landau resonances are observed near and above the ionization limit only in σ-polarization. Configuration interaction produces striking differences in the intensities and spacings of the n- and l-mixed spectra while only the shapes of the quasi-Landau resonances depend on the atomic systems.
ISSN:1364-5021
0080-4630
1471-2946
2053-9169
DOI:10.1098/rspa.1978.0142