TiO 2 -SiO 2 supported MnWO x catalysts by liquid-phase deposition for low-temperature NH 3 -SCR
NH -SCR is an environmentally important reaction for the abatement of NO from different resources. MnO -based catalyst has attracted significant attention due to the excellent activity. In this paper, a series of MnWO /TiO -SiO catalysts were prepared by liquid-phase deposition method. The catalysts...
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Veröffentlicht in: | Royal Society open science 2019-01, Vol.6 (1), p.180669 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | NH
-SCR is an environmentally important reaction for the abatement of NO
from different resources. MnO
-based catalyst has attracted significant attention due to the excellent activity. In this paper, a series of MnWO
/TiO
-SiO
catalysts were prepared by liquid-phase deposition method. The catalysts were characterized by N
adsorption/desorption, XRD, TEM, XPS, FT-IR, H
-TPR, TG and water adsorption capacity. The existence of SiO
improved the SO
and H
O resistance of the MnWO
/TiO
-SiO
catalyst without decreasing the NH
-SCR activity. Under the reaction conditions of 260°C and 60 000 ml g
h
gas hourly space velocity (GHSV), the NO conversion was kept stable at about 95% for 140 min on stream. The excellent performance of MnWO
/TiO
-SiO
catalyst is considered to be originated from the texture properties and active species dispersion improvement by SiO
in the support and low-temperature preparation. |
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ISSN: | 2054-5703 2054-5703 |
DOI: | 10.1098/rsos.180669 |