Synthesis and properties of 1,3-dithiole[6]dendralene analogs with two thiophene spacers inserted

Derivatives of a 1,3-dithiole[6]dendralene analog with two thiophene spacers inserted (2) have been successfully synthesized. Cyclic voltammetry and spectroelectrochemistry revealed that their redox behavior, based on the distribution of the positive charges, differed depending on the position and t...

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Veröffentlicht in:Chemistry letters 2024-06, Vol.53 (6)
Hauptverfasser: Misaki, Tomoya, Nishiwaki, Masataka, Ito, Toshiki, Ueda, Masafumi, Fujisaki, Masahiro, Yoshimura, Aya, Shirahata, Takashi, Hayashi, Minoru, Misaki, Yohji
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container_issue 6
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container_title Chemistry letters
container_volume 53
creator Misaki, Tomoya
Nishiwaki, Masataka
Ito, Toshiki
Ueda, Masafumi
Fujisaki, Masahiro
Yoshimura, Aya
Shirahata, Takashi
Hayashi, Minoru
Misaki, Yohji
description Derivatives of a 1,3-dithiole[6]dendralene analog with two thiophene spacers inserted (2) have been successfully synthesized. Cyclic voltammetry and spectroelectrochemistry revealed that their redox behavior, based on the distribution of the positive charges, differed depending on the position and the electronic effect of substituents on the 1,3-dithiole rings.
doi_str_mv 10.1093/chemle/upae104
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source Oxford University Press Journals All Titles (1996-Current)
title Synthesis and properties of 1,3-dithiole[6]dendralene analogs with two thiophene spacers inserted
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