Synthesis and properties of 1,3-dithiole[6]dendralene analogs with two thiophene spacers inserted

Derivatives of a 1,3-dithiole[6]dendralene analog with two thiophene spacers inserted (2) have been successfully synthesized. Cyclic voltammetry and spectroelectrochemistry revealed that their redox behavior, based on the distribution of the positive charges, differed depending on the position and t...

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Veröffentlicht in:	Chemistry letters 2024-06, Vol.53 (6)
Hauptverfasser:	Misaki, Tomoya, Nishiwaki, Masataka, Ito, Toshiki, Ueda, Masafumi, Fujisaki, Masahiro, Yoshimura, Aya, Shirahata, Takashi, Hayashi, Minoru, Misaki, Yohji
Format:	Artikel
Sprache:	eng
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Zusammenfassung:	Derivatives of a 1,3-dithiole[6]dendralene analog with two thiophene spacers inserted (2) have been successfully synthesized. Cyclic voltammetry and spectroelectrochemistry revealed that their redox behavior, based on the distribution of the positive charges, differed depending on the position and the electronic effect of substituents on the 1,3-dithiole rings.
ISSN:	0366-7022 1348-0715
DOI:	10.1093/chemle/upae104