Tagged-particle motion in quasi-confined colloidal hard-sphere liquids

We investigate the tagged-particle motion in a strongly interacting quasi-confined liquid using periodic boundary conditions along the confining direction. Within a mode-coupling theory of the glass transition we calculate the self-nonergodicity parameters and the self-intermediate scattering functi...

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Veröffentlicht in:Journal of statistical mechanics 2021-04, Vol.2021 (4), p.43301
Hauptverfasser: Schrack, Lukas, Petersen, Charlotte F, Caraglio, Michele, Jung, Gerhard, Franosch, Thomas
Format: Artikel
Sprache:eng
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Zusammenfassung:We investigate the tagged-particle motion in a strongly interacting quasi-confined liquid using periodic boundary conditions along the confining direction. Within a mode-coupling theory of the glass transition we calculate the self-nonergodicity parameters and the self-intermediate scattering function and compare them with event-driven molecular dynamics simulations. We observe non-monotonic behavior for the in-plane mean-square displacement and further correlation functions which refer to higher mode indices encoding information about the perpendicular motion. The in-plane velocity-autocorrelation function reveals persistent anti-correlations with a negative algebraic power-law decay t −2 at all packing fractions.
ISSN:1742-5468
1742-5468
DOI:10.1088/1742-5468/abee23