Improved performance of ternary organic solar cells based on both bulk and pseudo-planar heterojunction active layer

The high photovoltaic conversion efficiency (PCE) of ternary organic solar cells (OSCs) based on PTB7-Th, PC 71 BM and IEICO-4F material is obtained, the short-circuit current density ( J SC ), fill factor (FF), and open-circuit voltage is 25.90 mA cm −2 , 73.20% and 0.71 V, respectively. PCE is as high as 13.53%. It is the highest PCE of ternary OSCs based on PTB7-Th, PC 71 BM and IEICO-4F materials for all we know. The narrow bandgap material of IEICO-4F is deposited on PTB7-Th:PC 71 BM bulk heterojunction (BHJ) by layer-by-layer process. We constructed the dual bandgap active layer both BHJ and pseudo-planar heterojunction (P-PHJ), it could be defined as ternary BHJ/P-PHJ of OSCs. This type of OSCs is not only the complementary bandgap material of the active layer, but also increasing the donor/acceptor (D/A) interface. The excitons generation and collection of the device are increased leading a higher J SC and FF. The semitransparent OSCs (ST-OSCs) is prepared by varying the thickness of Ag electrode and PCE can reach 9.70%, and the average visible light transmittance and light use efficiency of ST-OSCs are improved effectively.