Laser surface nanocrystallization of oxide ceramics with eutectic composition: a comprehensive review

Nanoeutectic oxide layers have been obtained by laser surface nanocrystallization on oxide ceramics with eutectic composition. The eutectic layer can effectively improve the surface performance of oxide materials. This paper provides a comprehensive review of this promising technique. It includes the numerical simulation of temperature field in the melt pool associated with laser surface melting, formation mechanisms and growth kinetics of the coupled nanoeutectic structure, and the influence of processing parameters on structure and properties of eutectic oxide layer. In combination with other preparation techniques, such as directional solidification and additive manufacturing methods, the formation mechanism and prevention of bubbles and cracks are clarified. The relationship between microstructure and performance with gradient feature is also indicated. This review attempts to inspire imaginations and insights into material design and process optimization for laser surface nanocrystallization of oxide ceramics with eutectic composition.