Chemical Modification of PVC with Phenolic Groups

Chemical Modification of PVC with Phenolic Groups

The reaction of poly(vinyl chloride) with phenol was studied without catalysts at temperatures between 60 and 182°C. The reaction products were analyzed by NMR, IR and UV spectroscopy, elemental analysis, viscometry, osmometry, and OH groups determinations. The content of phenolic groups bound to po...

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Veröffentlicht in:Journal of macromolecular science. Part A, Pure and applied chemistry Pure and applied chemistry, 1995-02, Vol.32 (2), p.301-309
Hauptverfasser: Robilâ, Gabriela, Buruianâ, E. C., Caraculacu, A.
Format: Artikel
Sprache:eng
Schlagworte:
Applied sciences
Chemical modifications
Chemical reactions and properties
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
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Zusammenfassung:The reaction of poly(vinyl chloride) with phenol was studied without catalysts at temperatures between 60 and 182°C. The reaction products were analyzed by NMR, IR and UV spectroscopy, elemental analysis, viscometry, osmometry, and OH groups determinations. The content of phenolic groups bound to polymer chain increased with the reaction temperature. At the same time, some scissions of macromolecular chains can occur.
ISSN:1060-1325
1520-5738
DOI:10.1080/10601329508011163