Preferred Conformation of a New Ring B-Homo Diterpene, Rearrangement Product of Methyl 9α-Hydroxy-11α-Methanesulfonyloxy-(-)-Kauran-19-oate

The preferred conformation of a ring B-homo diterpene, obtained by the rearrangement of methyl 9α-hydroxy-11α-methanesulfonyloxy-(-)-kauran-10-oate 1 with potassium t-butoxide in t-butanol, was determined on the basis of the n.O.e. experiments and molecular dynamics calculations.

Bibliographische Detailangaben

Veröffentlicht in:	Natural product letters 1995-02, Vol.6 (1), p.63-68
Hauptverfasser:	Nakano, Tatsuhiko, Maillo, María Aracelis, Usubillaga, Alfredo, Troconis, Mary Cordero De
Format:	Artikel
Sprache:	eng
Schlagworte:	a ring B-homo kaurane derivative molecular dynamics calculations n.O.e preferred conformation
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!