Preferred Conformation of a New Ring B-Homo Diterpene, Rearrangement Product of Methyl 9α-Hydroxy-11α-Methanesulfonyloxy-(-)-Kauran-19-oate

Preferred Conformation of a New Ring B-Homo Diterpene, Rearrangement Product of Methyl 9α-Hydroxy-11α-Methanesulfonyloxy-(-)-Kauran-19-oate

The preferred conformation of a ring B-homo diterpene, obtained by the rearrangement of methyl 9α-hydroxy-11α-methanesulfonyloxy-(-)-kauran-10-oate 1 with potassium t-butoxide in t-butanol, was determined on the basis of the n.O.e. experiments and molecular dynamics calculations.

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Veröffentlicht in:Natural product letters 1995-02, Vol.6 (1), p.63-68
Hauptverfasser: Nakano, Tatsuhiko, Maillo, María Aracelis, Usubillaga, Alfredo, Troconis, Mary Cordero De
Format: Artikel
Sprache:eng
Schlagworte:
a ring B-homo kaurane derivative
molecular dynamics calculations
n.O.e
preferred conformation
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Zusammenfassung:The preferred conformation of a ring B-homo diterpene, obtained by the rearrangement of methyl 9α-hydroxy-11α-methanesulfonyloxy-(-)-kauran-10-oate 1 with potassium t-butoxide in t-butanol, was determined on the basis of the n.O.e. experiments and molecular dynamics calculations.
ISSN:1057-5634
DOI:10.1080/10575639508044089