Stereoselective Reactions of Allylic Hydroxy Phosphonates

Stereoselective Reactions of Allylic Hydroxy Phosphonates

The stereochemical outcome of the palladium catalyzed addition of nucleophiles to the carbonate derivative, the [3,3] rearrangement of the imidate and carbamate derivatives, and the epoxidation and cyclopropanation of hydroxy allylic phosphonates is presented.

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Bibliographische Detailangaben
Veröffentlicht in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1999-01, Vol.144 (1), p.181-184
Hauptverfasser: De La Cruz, M. Antonette, Shabany, Hossein, Spilling, Christopher D.
Format: Artikel
Sprache:eng
Schlagworte:
asymmetric
cyclopropanation
epoxidation
phosphonates
stereoselective
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Beschreibung
Zusammenfassung:The stereochemical outcome of the palladium catalyzed addition of nucleophiles to the carbonate derivative, the [3,3] rearrangement of the imidate and carbamate derivatives, and the epoxidation and cyclopropanation of hydroxy allylic phosphonates is presented.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426509908546212