SYNTHESE VON PHOSPHONAT-PHOSPHANEN DURCH REDUKTION

SYNTHESE VON PHOSPHONAT-PHOSPHANEN DURCH REDUKTION

Aliphatic and aromatic phosphonate-phosphanes 2 and 4, especially calix [4]arene derivatives, were obtained by PhSiH 3 reduction of phosphonate-phosphane oxides 1 and 3. The phosphonate group is stable under reducing conditions.

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Bibliographische Detailangaben
Veröffentlicht in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1997-12, Vol.131 (1), p.141-145
Hauptverfasser: Gloede, JÖRg, Ozegowski, Sigrid, Kökritz, Angela, Keitel, Iris
Format: Artikel
Sprache:eng
Schlagworte:
calixarene phosphanes
phosphonate-phosphanes
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Zusammenfassung:Aliphatic and aromatic phosphonate-phosphanes 2 and 4, especially calix [4]arene derivatives, were obtained by PhSiH 3 reduction of phosphonate-phosphane oxides 1 and 3. The phosphonate group is stable under reducing conditions.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426509708031602