Synthesis and Study of a Sulfur Heterocycle Fused p-Phenylene Vinylene Conducting Polymer

Synthesis and Study of a Sulfur Heterocycle Fused p-Phenylene Vinylene Conducting Polymer

Poly(benzo[1,2-b:4,5-b′]dithiophene-4,8-diyl vinylene) (1) has been prepared by the pyrolysis of the precursor polymer 2 and studied. Quantum mechanical calculations on the aromatic and quinoid monomers, oligomers and polymers indicate that 1 is a planar aromatic polymer.

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Veröffentlicht in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1994-10, Vol.95 (1-4), p.507-508
Hauptverfasser: Pomerantz, Martin, Wang, Jiping, Seong, Seeyearl, Starkey, Kyle P., Nguyen, Long, Marynick, Dennis S.
Format: Artikel
Sprache:eng
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Zusammenfassung:Poly(benzo[1,2-b:4,5-b′]dithiophene-4,8-diyl vinylene) (1) has been prepared by the pyrolysis of the precursor polymer 2 and studied. Quantum mechanical calculations on the aromatic and quinoid monomers, oligomers and polymers indicate that 1 is a planar aromatic polymer.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426509408034296