Unexpected Substitution Reactions of 1,3-Dithietane-1,1,3,3-Tetraoxide (Disulphene)
1,3-Dithietane-1,1,3,3-tetraoxide ("disulphene") is a versatile reagent for the synthesis of sulphenes and sulphines 1 . Upon investigating silylation reactions of disulphene (1) an unexpected O-silylation yielding a sulphoxoniumylide was found 2 . The synthesis of more stable sulphoxonium...
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| Veröffentlicht in: | Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1994-08, Vol.93 (1-4), p.477-478 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | 1,3-Dithietane-1,1,3,3-tetraoxide ("disulphene") is a versatile reagent for the synthesis of sulphenes and sulphines
1
. Upon investigating silylation reactions of disulphene (1) an unexpected O-silylation yielding a sulphoxoniumylide was found
2
. The synthesis of more stable sulphoxoniumylides will be reported
3
. |
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| ISSN: | 1042-6507 1563-5325 |
| DOI: | 10.1080/10426509408021911 |